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The total synthesis of 14 membered macrolide Pestalotioprolide C and C7- epi - Pestalotioprolide C were accomplished starting from commercially available D-Mannitol by Stereoselective synthetic approach. The key reactions involved are Mitsunobu reaction, Regioselective ring opening of chiral epoxide and ring-closing metathesis reactions (RCM).

Stereoselective total synthesis of Pestalotioprolide C and C7- epi -Pestalotioprolide C