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Cycl[3.2.2]azine molecules are widely found in both synthetic chemistry and natural products. They have shown promising applications in a variety of research fields. The development of facile and stereoselective methods for the synthesis of cycl[3.2.2]azine derivatives has attracted great interests in recent years. Representative acheivements in the construction of cycl[3.2.2]azine molecules in both enantioselective and non-asymmetric fahsion are systematically reviewed.

Synthetic methods for the construction of cycl[3.2.2]azine molecules