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Densities ( ρ ) and dynamic viscosity () of the binary mixtures haloarenes (2-chlorotoluene ( o- CT) or 4-chlorotoluene ( p- CT) or 1,3-dichlorobenzene ( m- DCB)) (1) + cyclohexane (2) were experimentally measured at T = (298.15–318.15) K and atmospheric pressure. The excess molar volumeand deviation in dynamic viscositywere calculated using  ρ  anddata. Thevalues for  o -CT or  p- CT or  m- DCB (1) + cyclohexane (2) are negative at all compositions. Theis a temperature dependent property. Thevalues decreases as temperature rise. Thevalues were analysed using Prigogine-Flory-Patterson (PFP) theory too. Thevalues are negative at all compositions. The viscosity increases with the rise in temperature because of the opening of interstitial voids in mixture. Singh equation and Bloomfield and Dewan (BFD) model were applied to predictandvalues. The viscosities of binary mixtures have been predicted using different correlations.

Thermodynamic modelling of density and viscosity data of binary mixtures of haloarenes with cyclohexane