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In this paper, we have investigated partial and total integral ionisation cross-sections of CF 3 Cl and CF 2 Cl 2  molecules by a modified Jain-Khare semi-empirical approach during the direct and dissociative ionisation by electron impact. Present results show good agreement with the available data. Besides integral ionisation cross-sections, for the first time, we evaluated partial and total single differential cross sections for these molecules. No other results are available for single differential cross sections to compare the present calculated results.

Electron ionisation cross sections of CF 3 Cl and CF 2 Cl 2 molecules