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Mn doped CaZrO 3 -NaNbO 3  solid solutions were prepared by a conventional solid reaction method. Mn doping can reduce leakage current significantly and the optimized content is 3% (mole). For Mn doped CaZrO 3 -NaNbO 3  solid solutions, the antiferroelectricity is stabilized when the content of CaZrO 3  is less than 6% (mole) When the content of CaZrO 3  is higher than 6% (mole), the polarization decreases, the polarization-electric hysteresis loop becomes slim, and the antiferroelectric-antiferroelectric related dielectric peak disappears, indicating antiferroelectric ordering is destroyed.

Dielectric and antiferroelectric properties of Mn-doped CaZrO 3 -NaNbO 3 ceramics