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For the first time, the dielectric relaxation and domain-wall freezing are reported for the single crystal of (CH 3 NH 3 ) 5 Bi 2 Cl 11  ferroelectric, which was tested in wide ranges of frequency (1 Hz–1 GHz) and temperature (50–350 K). The results demonstrated two relaxation regions obeying the Arrhenius and Vogel-Fulcher-Tammann laws. The freezing temperature was estimated at 86,3 K using extrapolation method.

Dielectric relaxation and domain-wall freezing in (CH 3 NH 3 ) 5 Bi 2 Cl 11 ferroelectric crystal