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A new compound with formulation 0.4[Pb(Fe 0.5 Nb 0.5 )O 3 ] −0.6[(Ba 0.8 Sr 0.2 )TiO 3 ] was prepared by solid state route. The structural properties were analyzed by X-ray diffraction in terms of POWD and Rietveld analyses. X-ray photoelectron spectroscopy study provides for electronic structure. Structural vibrations and chemical compositions were analyzed by FTIR and Raman spectroscopy. Morphological and elemental analyses were done by FESEM and EDS studies. UV–Visible analysis was done to study the narrow band gap, effect of oxygen vacancy and Urbach energy. Dielectric characteristics show the diffuse phase transition. The room temperature multiferroicity was confirmed by P-E and M-H loop studies.

Electronic structure, optical and electrical characteristics of multiferroic [Pb(Fe 0.5 Nb 0.5 )O 3 ] 0.4 –[(Ba 0.8 Sr 0.2 )TiO 3 ] 0.6