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A ferroelectric solid solution of a three-component system of 0.90NaNbO 3  − 0.05KNbO 3  − 0.05CdNb 2 O 6  was prepared by means of a two-stage solid-phase synthesis with subsequent sintering based on conventional ceramic technology. An X-ray diffraction study was carried out, and unit-cell parameters of the solid solutions with the aforementioned composition were determined. The two-phase states and related non-180° domain (or twin) structures are analyzed for the same lead-free composition. A tendency of the ferroelectric tetragonal phase to a monodemonization in the heterophase structures is discussed.

ferroelectrics

Analysis of non-180° domain structures in lead-free ferroelectric solid solutions based on NaNbO 3  and KNbO 3 , perovskites and CdNb 2 O 6  coulombite