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Polycrystalline compounds of Sn substituted Pb 0.9 Mn 0.1 (Zr 0.52 Ti 0.48 ) 1-x Sn x  O 3  (where x = 0.05,0.1) are synthesized by conventional ceramic method. Raman spectroscopy study reveals the tetragonal structure of Sn substituted samples. Impedance spectroscopic studies reveal the non-Debye kind of relaxation process in the material. Grain and grain contribution to the electrical conduction was observed. The observed P-E hysteresis confirmed the ferroelectric nature of all the samples. With the increase of Sn doping, Pr, Ps and Ec values also increased.

Enhanced ferroelectric properties in B-site Sn doped Pb 0.9 Mn 0.1 Zr 0.52 Ti 0.48 O 3