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SmFeO 3  (SFO) is a highly challenging rear earth orthoferrites system for future modern spintronics applications and data storage devices due to its outstanding dielectric and ferroelectric properties, among other RFeO 3  members. In the present attempt, Ce doped SFO system with compositions Sm 1-x Ce x FeO 3  (where x = 0.02 to 1) is explored to reveal its structural and ferroelectrics behavior in view to check its suitability for data storage applications. The systems were synthesized by a sol-gel method based on glycine gel reaction. The structural features of the as-synthesized samples are fitted by Rietveld refinement of x-ray diffraction patterns, which confirms an orthorhombic phase with pbnm space group. Temperature driven ferroelectric properties of Sm 1-x Ce x FeO 3  (where x = 0.02 to 1) were studied. Ce doped SmFeO 3  indicates a reduction in losses and leakage current by Ce doping, suggesting that it is a promising material to explore as room temperature multiferroics.

ferroelectrics

Synthesis of pure phase SmFeO 3  orthoferrites via self-propagating sol-gel combustion synthesis and study of Ce doping effect on their ferroelectric properties