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Ceramics of the ternary solid solution system 0.3BiFeO 3 –0.5PbFe 0.5 Nb 0.5 O 3 –0.2PbTiO 3  were prepared by the conventional solid-phase reaction method. It was found that at room temperature the samples had a tetragonal structure, which transformed into a cubic with increasing temperature. The grain structure, dielectric and piezoelectric characteristics of the obtained ceramics were studied. The piezoelectric coefficient  d33  = 260 pC/N was obtained. It was found that this solid solution demonstrated behavior typical for ferroelectric relaxors with a phase transition in the temperature range of 420 – 430°K. An explanation of the observed effects is given.

Structure and high piezoelectric response of the ternary 0.3BiFeO 3 -0.5PbFe 0.5 Nb 0.5 O 3 -0.2PbTiO 3 ceramics