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Changes in the flammability characteristics of a combusting mixture and its ‘dilution’ levels – characterized, respectively, by the mixture’s equivalence ratio and residual gas fraction – can have significant impacts on the nature of combustion in internal combustion engines. These combustion changes can manifest as variations in combustion phasing and repeatability, and affect engine efficiency, emissions, and performance. The current work uses experimental, high-speed, in-cylinder CO 2  concentration data from a single-cylinder, natural gas-fueled engine to track compositional variations in the combusting mixture; and then uses a chemical kinetics solver to isolate the effects of flammability and dilution changes on the mixture’s ‘reactivity,’ which is characterized by its laminar flame speed (LFS) and ignition delay (ID). It is found that LFS changes are driven strongly by the trapped equivalence ratio, while ID changes are driven primarily by dilution and pressure changes. Additionally, the effects of LFS changes on the overall combustion phasing are found to be more pronounced than those from ID changes, as the former influences both the combustion initiation and propagation processes.

Effects of Dilution and Flammability Changes on Mixture Reactivity in a Natural Gas Internal Combustion Engine