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The electronic characteristics, surface topography, and surface roughness of a Ti-3Cu alloy were investigated in phosphate buffered saline (PBS) containing bovine serum albumin (BSA) at 37 °C and pH 7.4 ± 0.2 by Mott-Schottky analysis (MSA) and atomic force microscopy (AFM). The n-type oxide layer was produced on the Ti-3Cu alloy surface due to the formation of oxygen-deficient TiO 2-x  barrier layer with interstitial copper asAs the serum-protein concentration increased from 1 g/L to 6 g/L in the phosphate buffered saline, the donor densities (N D ) of the semiconducting oxide layer decreased. The accumulation of serum protein observed by atomic force microscopy became the driving force in the restructuring of the oxide film via chemisorption and caused a reduction in the donor densities. The change in the magnitude of the nano-roughness suggested chemisorption which is beneficial for the osseointegration of Ti-3Cu implants.

analytical letters

Characterization of the Influence of Bovine Serum Albumin (BSA) upon the Electronic Properties and Surface Topography of a Ti-3Cu Biomedical Alloy by Mott-Schottky Analysis (MSA) and Atomic Force Microscopy (AFM)