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The double-proton-transfer process in the C2h 7-azaindole (7AI) dimer in the first singlet excited state has changed from the widely accepted concerted process (1, 2) to being regarded as stepwise (3) with a polar intermediate, which depends on the environmental polarity. In this recent work Kwon and Zewail (3) reported in acetonitrile at room …

On the concerted mechanism of photo-induced biprotonic transfer in C 2h 7-azaindole dimer

On the concerted mechanism of photo-induced biprotonic transfer in C _2h 7-azaindole dimer