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The perovskite structure material La 0.35 Sr0.6 MnO 3 was sintered in air andthe mixed ceramic of a 0.35 Sr 0.6MnO 3 and 8 mol % Y 2 O3 +ZrO 2 with a 1:1 mass ratewas also sintered in air, both at 1530 K for 12 hour. The AC complex impedancespectra have been measured and the effect of the interface between La0.35 Sr 0.6 MnO3 and YSZ on dielectric relaxation properties of La0.35 Sr 0.6 MnO3 has been investigated. A schematic of diffusion phaseformation and the equivalent circuits are proposed for explaining the results.In the complex impedance spectra, the first and second semicircles correspondto the grain-boundary and interface respectively. The results show that thedielectric relaxation properties and structure of the mixed ceramic aredifferent to that of single phase La 0.35 Sr0.6 MnO 3 . The interface has animportant effect on the electric properties of the mixed ceramic and producesa dielectric relaxation in low frequency.

Effect of Interfaces on Dielectric Relaxation in La0.35Sr0.6MnO3 -YSZ