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It is shown that theparameter m in the Grunwald-Winstein equation, log(k/k0) = mY, can be equated to z/z0where z0 is the chargeseparation in the transition state of solvolysis of t-butyl chloride in a givenpair of solvents and z is the charge separation in the transition state of areaction in which only neutral molecules are involved as reactants in the samepair of solvents.

Charge Separation in Transition States of Reactions Involving Neutral Molecules as Reactants