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Magnetic data have beenobtained for ruthenium(III) chelates of the fluorinated monothio-β-diketonesRC(SH)=CHCOCF3 (R = 2-thienyl, β- naphthyl,Ph,p-MeC6H4, m-MeC6H4, m-ClC6H4,m-BrC6H4).The compounds are low-spin (S = 1/2) withmoments in the range 1.68-1.84 B.M. at room temperature; the moments decreasewith decrease in temperature.

Thio derivatives of β-diketones and their metal chelates. XX. Magnetic moments of some ruthenium(III) chelates of fluorinated Monothio-β-diketones