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From the study of the cell Ag-AgCl|KCl(m3), KA(m2), HA(m1), QH2-Q|Pt (where HA stands for acid) the ionization constants of chloroacetic acid in formamide have been determined at 25, 30 and 35°, and those of phenylacetic acid at nine different temperatures in the range 5-45°. The cell Pt, H2|HA(m1), KA(m2), KCl(m3)|AgCl-Ag has also been used to redetermine the ionization constants of chloroacetic acid in formamide in the range 5-45°; the ionization constants of chloroacetic are in good agreement with those of an independent study. The effect of substituents on the strength of acetic acid has been examined in formamide.

australian journal of chemistry

Studies on the application of the quinhydrone electrode in formamide. V. The ionization constants of chloro- and phenyl-substituted acetic acids from E.M.F. measurements at different temperatures and the effect of substituents on the strength of acetic acid in formamide