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Lithium tri-t-butoxyhydroaluminate, sodium tetrahydroborate and lithium tetrahydroborate, in stoichiometric amounts, reduce benzaldehyde in the presence of acetophenone or butanal in the presence of butanone. Lithium tetrahydroaluminate and lithium cyanatohydroborate are less selective.

Competitive reduction of aldehyde-ketone mixtures by complex hydroborates and hydroaluminates