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The binuclearbis-ortho-metallated complex( O C ) ~ M ~ C ~ H ~ N = NC ~ H ~ M ~ ( C O ) ~ - Ihas been obtained from areaction between MnMe(CO)5 and Mn(C6H4N=NPh)(C0)4; the reactionbetween azobenzene andMnPh(CO)$ affords (PhN-NHC,H4)Mn2(C0)6.

Cyclometallation reactionds. VIII. Binuclear manganese carbonyl complexes derived from azobenzene