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This work introduces a sticky-charge wall model as a simple and intuitiverepresentation of charge regulation. Implemented within the mean-field level ofdescription, the model modifies the boundary conditions without affecting theunderlying Poisson-Boltzmann (PB) equation of an electrolyte. Employing variousmodified PB equations, we are able to assess how various structural details ofan electrolyte influence charge regulation.

General theory of charge regulation within the Poisson-Boltzmann framework: study of a sticky-charged wall model