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We present X-ray absorption spectroscopy and resonant inelastic X-rayscattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueousferricyanide. These measurements demonstrate the ability of high-throughputtransition-edge-sensor (TES) spectrometers to access the rich soft X-ray(100-2000eV) spectroscopy regime for dilute and radiation-sensitive samples.Our low-concentration data are in agreement with high-concentrationmeasurements recorded by conventional grating-based spectrometers. Theseresults show that soft X-ray RIXS spectroscopy acquired by high-throughput TESspectrometers can be used to study the local electronic structure of dilutemetal-centered complexes relevant to biology, chemistry and catalysis. Inparticular, TES spectrometers have a unique ability to characterize frozensolutions of radiation- and temperature-sensitive samples.

L-Edge Spectroscopy of Dilute, Radiation-Sensitive Systems Using a Transition-Edge-Sensor Array