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A key property of glass forming alloys, the anomalously small volumedifference with respect to the crystal, is shown to arise as a directconsequence of the soft repulsive potentials between metals. This feature ofthe inter-atomic potential is demonstrated to be responsible for a significantcomponent of the glass forming ability of alloys due to the decrease in theenthalpy of fusion and the associated depression of the freezing point.

Density and Glass Forming Ability in Amorphous Atomic Alloys: the Role of the Particle Softness