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The electronic properties of co-evaporated mixtures (blends) of manganesephthalocyanine and the fullerene C$_{60}$ (MnPc:C$_{60}$) have been studied asa function of the concentration of the two constituents using two supplementaryelectron spectroscopic methods, photoemission spectroscopy (PES) as well aselectron energy-loss spectroscopy (EELS) in transmission. Our PES measurementsprovide a detailed picture of the electronic structure measured with differentexcitation energies as well as different mixing ratios between MnPc andC$_{60}$. Besides a relative energy shift, the occupied electronic states ofthe two materials remain essentially unchanged. The observed energy levelalignment is different compared to that of the related CuPc:C$_{60}$ bulkheterojunction. Moreover, the results from our EELS investigations show thatdespite of the rather small interface interaction the MnPc related electronicexcitation spectrum changes significantly by admixing C$_{60}$ to MnPc thinfilms.

Electronic properties of Mn-Phthalocyanine - C$_{60}$ bulk heterojunctions: combining photoemission and electron energy-loss spectroscopy