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The bistable NH3 + O2 reaction over a Rh(110) surface was explored in the pressure range 10−6 -10−3 mbar and in the temperature range 300-900 K using photoemission electron microscopy and low energy electron microscopy as spatially resolving methods. We observed a history dependent anisotropy in front propagation, traveling interface modulations, transitions with secondary reaction fronts, and stationary island structures.Fil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina. Leibniz-Universität Hannover; AlemaniaFil: Borkenhagen, Benjamin. Technische Universität Clausthal; AlemaniaFil: Lilenkamp, Gerhard. Technische Universität Clausthal; AlemaniaFil: Lovis, Florian. Leibniz-Universität Hannover; AlemaniaFil: Smolinsky, Tim. Leibniz-Universität Hannover; AlemaniaFil: Imbihl, Roland. Leibniz-Universität Hannover; Alemani

Traveling interface modulations and anisotropic front propagation in ammonia oxidation over Rh(110)