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We report on the single phase synthesis and room temperature structuralcharacterization of PbFe0.67W0.33O3 (PFW) multiferroic. The PFW was synthesizedby low temperature sintering, Columbite method. Analysis of powder XRD patternexhibits single phase formation of PFW with no traces of pyrochlore phase.Detailed analysis of room temperature neutron diffraction (ND) reveals cubicphase at room temperature, space group Pm-3m. The ND pattern clearly revealsmagnetic Bragg peak at 2theeta = 18.51 (Q = 1.36{\AA}-1). The refinement ofmagnetic structure reveals G-type antiferromagnetic structure in PFW at roomtemperature. The dielectric constant and loss tangent decreases with increasingfrequency. The room temperature P-E measurements shows a non-linear slimhysteresis, typical nature of relaxor multiferroics, with saturation andremnant polarizations of Ps = 1.50 microC/cm2 and Pr = 0.40 microC/cm2,respectively.

Neutron Diffraction Studies on Chemical and Magnetic Structure of Multiferroic PbFe0.67W0.33O3