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Thermal variation of structural property, linear thermal expansioncoefficient, resistivity, thermopower and power factor of polycrystallineBi1-xSbx (x=0.10, 0.14) samples are reported. Temperature-dependent powderdiffraction experiments indicate that samples do not undergo any structuralphase transition. Rietveld refinement technique has been used to performdetailed structural analysis. Temperature dependence of thermal expansioncoefficient is found to be stronger for Bi0.90Sb0.10. Also, power factor fordirect band gap Bi0.90Sb0.10 is higher as compared to that for indirect bandgap Bi0.86Sb0.14. Role of electron-electron and electron-phonon scattering onresistivity, thermopower and power factor have been discussed.

Temperature-dependent structural property and power factor of n type thermoelectric Bi0.90Sb0.10 and Bi0.86Sb0.14 alloys