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Epitaxial Mn-doped BiFeO3 (MBFO) thin films were grown on GaAs (001)substrate with SrTiO3 (STO) buffer layer by pulsed laser deposition. X-raydiffraction results demonstrate that the films show pure (00l) orientation, andMBFO(100)//STO(100), whereas STO (100)//GaAs (110). Piezoresponse forcemicroscopy images and polarization versus electric field loops indicate thatthe MBFO films grown on GaAs have an effective ferroelectric switching. TheMBFO films exhibit good ferroelectric behavior (2Pr ~ 92 {\mu}C/cm2 and 2EC ~372 kV/cm). Ferromagnetic property with saturated magnetization of 6.5 emu/cm3and coercive field of about 123 Oe is also found in the heterostructure at roomtemperature.

Heteroepitaxial Growth and Multiferroic Properties of Mn-doped BiFeO3 films on SrTiO3 buffered III-V Semiconductor GaAs