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We studied the electronic structure of a conventional superconductor, ZrB(12)using high resolution x-photoemission spectroscopy and single crystallinesamples. Experimental results with different bulk sensitivity reveals borondeficiency and different valence states of Zr at the surface relative to thebulk. Signature of a satellite features is observed in the Zr core levelspectra corresponding to the bulk of the material suggesting importance ofelectron correlation among the conduction electrons in the bulk while thesurface appears to be uncorrelated. These results provide an insight infabricating devices based on such superconductors.

Surface bulk differences in a conventional superconductor, ZrB(12)