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(CaCuO2)m/(La0.7Sr0.3MnO3)n superlattices, consisting of the infinite layerscuprate CaCuO2 and the optimally doped manganite La1-xSrxMnO3, were grown bypulsed laser deposition. The transport properties are dominated by themanganite block. X-Ray Absorption spectroscopy measurements show a clearevidence of an orbital reconstruction at the interface, ascribed to thehybridization between the Cu 3d3z2-r2 and the Mn 3d3z2-r2 orbitals viainterface apical oxygen ions. Such a mechanism localizes holes at theinterfaces, thus preventing charge transfer to the CaCuO2 block. Some charge(holes) transfer occurs toward the La0.7Sr0.3MnO3 block in strongly oxidizedsuperlattices, contributing to the suppression of the magnetotransportproperties.

Charge localization at the interface between La1-xSrxMnO3 and the infinite layers cuprate CaCuO2