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Measured and calculated rotationally resolved photoelectron spectra for photoionization of low rotational levels of the C^1B_1 Rydberg state of water are reported. This is the first example of rotationally resolved photoionization spectra beyond the special cases of H_2, high-J levels, and threshold spectra. These spectra reveal very nonatomiclike behavior and, surprisingly, the influence of multiple Cooper minima in the photoelectron matrix elements.

Rotationally resolved energy-dispersive photoelectron spectroscopy of H2O: Photoionization of the C̃(0,0,0) state at 355 nm