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The investigation of the electronic conduction through monosulfurdiarylethene (1S-DE) immobilized in an insulating dodecanethiol matrix on a goldsurface was addressed. Scanning tunnelingspectroscopy allows to probe spatially the frontier molecular orbitals of 1S-DE at 77 K. We locally extracted the electronic highest occupied molecular orbital-lowest unoccupied molecular orbital gap of 1S-DE with the value of 1.56 eV. This attempt reveals the importance of scanning tunnelingspectroscopy as a tool to measure the charge transport properties of diarylethene towards the realization of a switching-based molecular device

Electronic properties of individual diarylethene molecules studied using scanning tunneling spectroscopy