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Detailed quasiclassical trajectory calculations of the D+H2(v=0, j=0)→HD(v′=0, j′)+H have been carried out in the range of collision energy from 0.35 to 1.25 eV. The calculated v′j′ state resolved differential cross sections and opacity functions show analogous structures to the ones obtained by accurate quantum mechanical results, that is, a peak along a line in the E−θ (or E−J) plane, that was attributed to broad resonances. Analysis of present results in terms of the duration of the collision indicates that those trajectories pertaining to these peaks proceed through the formation of short lived collision complexes with lifetimes of 15–35 fs. © American Institute of PhysicsPartly financed by the CICYT of Spain under Grant No. PB890041.Peer Reviewe

Classical collision complexes in the D+H2(v=0, j=0)→HD(v′, j′)+H reaction