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Measurements of heats of transport are reported for binary liquid mixtures containing carbon tetrachloride and benzene, toluene, 2‐propanone, n‐hexane, or n‐octane at 298 K and ambient pressure. Additionally, measurements were made at 308 K for carbon tetrachloride with benzene, toluene, and 2‐propanone. The corresponding heat‐mass Onsager coefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. These data will be used in a companion paper to report a modified Enskog method for correlation and prediction of heats of transport.

the journal of chemical physics

Heats of transport from diffusion thermoeffect measurements on binary liquid mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, <i>n</i>-hexane, and <i>n</i>-octane

Heats of transport from diffusion thermoeffect measurements on binary liquid mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and n-octane