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By using SCF and stabilization‐like procedures, we have located a (π, π*) singlet resonance‐like state in ethylene at 10.21 eV. This state is embedded in the ionization continuum and carries an oscillator strength of 0.46 and is probably the analog to the spectroscopic V state in Hartree–Fock theory. Implications of these results for other systems are discussed.

An SCF-stabilization approach to excited states embedded in the continuum