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Linear spectropolarimetry is a powerful tool to probe circumstellarstructures on spatial scales that cannot yet be achieved through directimaging. In this review I discuss the role that emission-line polarimetry canplay in constraining geometrical and physical properties of a wide range ofcircumstellar environments, varying from the accretion disks around pre-mainsequence T Tauri and Herbig Ae/Be stars, to the issue of stellar wind clumping,and the aspherical outflows from the massive star progenitors of supernovae andlong gamma-ray bursts at low metallicity.

Linear Spectropolarimetry and the Circumstellar Media of Young and Massive Stars