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Frequency dependent dynamic electromechanical response of the mixedionic-electronic conductor film to a periodic electric bias is analyzed fordifferent electronic and ionic boundary conditions. Dynamic effects of mobileions concentration (stoichiometry contribution), charge state of acceptors(donors), electron concentration (electron-phonon coupling via the deformationpotential) and flexoelectric effect contribution are discussed. A variety ofpossible nonlinear dynamic electromechanical response of MIEC films includingquasi-elliptic curves, asymmetric hysteresis-like loops with pronounced memorywindow and butterfly-like curves are calculated. The electromechanical responseof ionic semiconductor is predicted to be a powerful descriptor of localvalence states, band structure and electron-phonon correlations that can bereadily measured in the nanoscale volumes and in the presence of strongelectronic conductivity.

Frequency Dependent Dynamical Electromechanical Response of Mixed Ionic-Electronic Conductors