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Resonance Raman spectra of DNA-wrapped single-walled carbon nanotubes films were studied at 5 and 295K in the range of radial-breathing (175–320cm−1) and tangential (1520–1625cm−1) modes. The spectra were compared with those of nanotubes in bundles. At 5K in the spectrum of film an upshift of bands with respect to their spectrum at high temperature and the intensity redistribution among bands of two samples were observed. The magnitude of this upshift depends on the nanotube type. The influence of a temperature decrease, the environment, and the electron-phonon coupling on the Raman spectrum of nanotubes are discussed.

Raman spectroscopy of DNA-wrapped single-walled carbon nanotube films at 295 and 5K