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Though intuitively appealing, the concept of spinodal is rigourously definedonly in systems with infinite range interactions (mean field systems). Inshort-range systems, a pseudo-spinodal can be defined by extrapolation ofmetastable measurements, but the point itself is not reachable because it liesbeyond the metastability limit. In this work we show that a sensible definitionof spinodal points can be obtained through the short time dynamical behavior ofthe system deep inside the metastable phase, by looking for a point where thesystem shows critical behavior. We show that spinodal points obtained by thismethod agree both with the thermodynamical spinodal point in mean field systemsand with the pseudo-spinodal point obtained by extrapolation ofmeta-equilibrium behavior in short range systems. With this definition, apractical determination can be achieved without regard for equilibrationissues.

Non-equilibrium Characterization of Spinodal Points using Short Time Dynamics