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The resonant Raman scattering in N-IR - UV range from amorphous hydrogenatedcarbon (a-C:H) reveal inclusions of trans-polyacetylene (trans-(CH)x) chainswith approximate length of up to 120 C=C units and inclusions ofpoly(p-phenylene vinylene) (PPV) polymer chains. The PPV is evidenced by astrong dispersive mode at ca. 1175 cm-1. It was found that the Raman responsefrom core Ag trans-(CH)x modes incorporated into a-C:H to changing excitationenergy is identical to of free-standing chains thus facilitating identificationof trans-(CH)x in complex carbonaceous materials spectra.

Resonant Raman scattering from polyacetylene and poly(p-phenylene vinylene) chains included into hydrogenated amorphous carbon