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We prepare a quantum state where each site of an optical lattice is occupiedby exactly one molecule. This is the same quantum state as in a Mott insulatorof molecules in the limit of negligible tunneling. Unlike previous Mottinsulators, our system consists of molecules which can collide inelastically.In the absence of the optical lattice these collisions would lead to fast lossof the molecules from the sample. To prepare the state, we start from a Mottinsulator of atomic 87Rb with a central region, where each lattice site isoccupied by exactly two atoms. We then associate molecules using a Feshbachresonance. Remaining atoms can be removed using blast light. Our method doesnot rely on the molecule-molecule interaction properties and is thereforeapplicable to many systems.

A Mott-like State of Molecules