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Electric-field-induced electronic state g/u mixing of nearly isoenergetic rovibrational levels of the E0g+(3P2) and D0u+(3P2) ion-pair states of I2 has been observed using optical triple resonance combined with resonance ionization. Detectable mixing with applied fields of 1 kV/cm occurs over a range of energy level separations of &lt; or = 0.3 cm(-1).

Electric-field-induced g/u mixing of the E0g+(3P2) and D0u+(3P2) ion-pair states of jet-cooled I2 observed using optical triple resonance