English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Open

Presents the pdf analysis as premium feature

PDF Analysis

Insights

Presents the summarisation as premium feature

Summarisation

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

The results of two separate studies of the complex between NO and N₂ are reported. The (1+1) REMPI spectrum of the Ã ← X˜ transition of the complex between NO and N₂ is presented of improved quality over that reported previously, and the appearance of the spectrum is discussed. The results of high-level ab initio calculations [RCCSD(T)/aug-cc-pVQZ//QCISD/6-311+G(2d)] on the X˜² II state are also reported. The indications are that the NO moiety is more freely rotating in the complex than is N₂, and that a wide angular space is sampled in the zero-point energy level.  The appearance of the REMPI spectrum suggests that the Ã ² Σ⁺ state is (close to) linear, and RCCSD(T)//QCISD calculations on the Ã state, using Rydberg-function-augmented basis sets, suggest that the lowest energy linear isomer is the ON N₂linear orientation. It is clear, however, that the understanding of this complex, and its spectroscopy, is far from complete, and will be challenging.Department of Applied Biology and Chemical TechnologyAuthor name used in this publication: Stuart D. Gambli

The Ã←X̃(1+1)REMPI spectrum and high-level ab initio calculations of the complex between NO and N2