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We develop a model of chemical equilibrium mixtures containing the elements H, C, F. We show that the shock response of a wide variety of molecular and polymeric fluorocarbons can be modeled as a chemical equilibrium mixture of a small number of dissociation product molecules. HF is known to strongly associate in the supercritical fluid phase. We predict that such an association also occurs under shock conditions.

The equation of state of HF under shock compression