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The unique tricarbocyclic system in GKK1032A 2 , an antitumor agent from Penicillium sp. GKK1032, was constructed in a highly stereoselective manner, starting from a readily available Hajos-Wiechert ketone analog.

synlett

Studies toward the Total Synthesis of GKK1032A<sub>2</sub>, a Structurally Unique Anti­tumor Compound: Stereoselective Construction of the Tricarbocyclic System

Studies toward the Total Synthesis of GKK1032A2, a Structurally Unique Anti­tumor Compound: Stereoselective Construction of the Tricarbocyclic System

Studies toward the Total Synthesis of GKK1032A₂, a Structurally Unique Antitumor Compound: Stereoselective Construction of the Tricarbocyclic System