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(A) BOX [(R)-2]-metal complex has been used in highly enantioselective, Mannich reactions 1 8 of a variety of carbonyl compounds with an N-tosyl-α-imino ester to efficiently produce a range of highly functionalized 4-oxo-glutamic acid ester derivatives, which were further used to prepare optically active α-amino-γ-lactones.

Bisoxazoline (BOX) Ligand-Metal Complexes:An Emerging Chiral Catalyst