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The ruthenium-catalyzed olefin cross-metathesis between pinacol allylboronate, CH 2 =CHCH 2 B(O 2 C 2 Me 4 ), and RCH=CH 2 giving RCH=CHCH 2 B(O 2 C 2 Me 4 ) was carried out in refluxing CH 2 Cl 2 in the presence of an alkylidene-ruthenium complex (3 mol%).

Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross-Metathesis between Pinacol Allylboronate and Terminal or Internal Alkenes