English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Pro

Presents the zaia usage as premium feature

ZAIA

Presents AI Discovery search usage as a premium feature

AI Discovery

Presents AI Discovery explain and summary usage as a premium feature

Content Analysis

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Presents the pdf analysis as premium feature

PDF Analysis

1500 Top-up

3000 Top-up

Zendy Basic

2500 Top-up

Zendy Unlimited

Presents the access of premium content as premium feature

Premium Content

Significance: Homoallylic azides and cyanides are synthesized in enantioenriched form through a palladium-catalyzed decarboxylative allylation on indanones. These functional groups had seen little (CN) to no (N3) reported use in the title reaction. Comment: The products are obtained in very good yield and mostly with high enantioselectivity. The starting materials can be synthesized in one step from the corresponding β-keto esters using hypervalent iodine reagents developed in the authors’ laboratories. Pd2(dba)3 (2.5–5 mol%) ligand (5.5–11 mol%)

Azides and Nitriles in Palladium-Catalyzed Decarboxylative Allylation