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Significance: Homoallylic azides and cyanides are synthesized in enantioenriched form through a palladium-catalyzed decarboxylative allylation on indanones. These functional groups had seen little (CN) to no (N3) reported use in the title reaction. Comment: The products are obtained in very good yield and mostly with high enantioselectivity. The starting materials can be synthesized in one step from the corresponding β-keto esters using hypervalent iodine reagents developed in the authors’ laboratories. Pd2(dba)3 (2.5–5 mol%) ligand (5.5–11 mol%)

Azides and Nitriles in Palladium-Catalyzed Decarboxylative Allylation