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Room temperature adsorption of I 2 on the Ge(111) surface is found to break the initial c(2×8) adatom reconstruction as iodine preferentially occupies the on top substrate site, breaks the backbonds between the adatom and the substrate and thus removes the Ge adatoms. As this process continues a c(2×4), and modifications thereof, reconstruction is formed consisting of chains of I 2 molecules bound in almost T 1 sites with a I-I bond length of 3.6 A

Formation of an iodine zig-zag chain c(2 × 4) reconstruction on the Ge(111) surface