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Thermoset-based polymer matrix composites are widely used for production of intumescent fire protective coatings; many operational properties of such coatings can be further enhanced by means of nanoscale layers between matrix and disperse phases. The dependence between temperature of processing and temperature of glass transition of thermosetting matrix allows to produce gradient of glass transition temperature along the depth of the coating and lower exfoilation of char residue from steel substrate. In the present article we have offered the novel design scheme for such coating. Several results of laboratory and numerical experiments that are within the framework of the offered scheme are also presented. Application of the offered scheme allows to develop efficient fire protective coatings in purposely and precisely controlled manner.

Design of Nanomodified Intumescent Polymer Matrix Coatings: Theory, Modeling, Experiments